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Creators/Authors contains: "Wade Wolfe, M. W."

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  1. ; ; ; ; ; (, Chemical communications)
    Using a Lewis acid-quenched CF2Ph- reagent, we show C–C bond formation through nucleophilic addition reactions to prepare molecules containing internal –CF2– linkages. We demonstrate C(sp2)–C(sp3) coupling using both SNAr reactions and Pd-catalysis. Finally, C(sp3)–C(sp3) bonds are forged using operationally simple SN2 reactions that tolerate medicinally-relevant motifs. 
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